New prospects for “living” anionic polymerization of (meth) acrylic esters
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چکیده
منابع مشابه
Kinetics of Living Anionic Polymerization of Polystyrenyl Lithium in Cyclohexane
Living anionic polymer chains polymerized with organolithium initiators usually form aggregates through their Li ends in nonpolar solvents. This aggregation structure strongly affects the anionic polymerization (propagation) kinetics. In the conventional molecular picture, the aggregates are assumed to be chemically inert and the propagation occurs only though the dissociated unimers, which lea...
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The concept of anionic polymerization was first developed by Ziegler and Schlenk in early 1910. Their pioneering work on the polymerization of diene initiated with sodium metal set the stage for the use of alkali metal containing aromatic hydrocarbon complexes as initiators for various α-olefins. In 1939, Scott and coworkers used for the first time the alkali metal complexes of aromatic hydroca...
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ژورنال
عنوان ژورنال: Makromolekulare Chemie. Macromolecular Symposia
سال: 1990
ISSN: 0258-0322
DOI: 10.1002/masy.19900320107